UP TO 15 % DISCOUNT

Get Your Assignment Completed At Lower Prices

Plagiarism Free Solutions
100% Original Work
24*7 Online Assistance
Native PhD Experts
Hire a Writer Now
MS2016 Phase Transformation and Kinetics Assignment, NTU, Singapore Identify and sketch the planes (4 2 0) and (0 3 2) in both FCC and BCC Fe lattices
Posted on: 26th Sep 2022

MS2016 Phase Transformation and Kinetics Assignment, NTU, Singapore Identify and sketch the planes (4 2 0) and (0 3 2) in both FCC and BCC Fe lattices

AY2223 S1: MS2016 – CA1 (Take-Home Assignment)

Topics – Imperfections and Diffusion in Solids

1. Identify and sketch the planes (4 2 0) and (0 3 2) in both FCC and BCC Fe lattices.

(i) On those identified planes, sketch and identify the total number of octahedral and tetrahedral sites available for an interstitial atom to occupy.

(ii) Which plane has the lower surface energy in both systems? You can use planar packing density of both planes as an indicator or other means.

(iii) In FCC Fe system, on both these planes, assume that only one ½ 0 0 site is occupied (no other interstitial sites are filled). Write strain energy equation for these two scenarios. You don’t have to calculate anything, but identify the terms, directions, etc. in the equations.

(iv) Similar to Q1(iii), take BCC Fe and assume that only one ½ ½ 0 site is occupied on both those planes. Write strain energy equation for the two scenarios. No calculation needed, but identify the terms, directions, etc. in the equations.

2. Assume that in the below Fig. Q2 we are referring to substitutional solid solutions. Plot how the enthalpy, entropy and the total free energy vary for these two systems as you change the composition by substitutional defects. In which of these two cases, substitution is endothermic or exothermic process? For each system, plot all (enthalpy, entropy, total free energy) in sketch for comparison.

3. We have talked about F-center defect in the class. To get more insights into the broad color center defects category, discuss and elaborate the following:

(i) Take any two types of color center defects and explain the principles behind in detail.

(ii) Take any two systems as representative examples and elaborate the mechanisms of color centers in them. Discuss the crystal structures, mechanisms behind the color change, and their stability (in terms of color change and associated changes to crystal structure; that is, is the color change permanent or will it change back after the irradiation process, for instance?).

4. The crystal structure of a hypothetical compound A2B (A: cation with +1 charge and B: anion with –2 charge) can be simply visualized as an FCC lattice with all the tetrahedral sites occupied.

(i) Sketch the structure with atoms.

(ii) After diffusing one cation ‘C’ per unit cell (substitution), calculate the strain energy because of this event? What changes are expected in this cell (that is, type of defects that are forming) and also list down the new chemical formula of this system (if any change to the original is seen)?

(iii) If one ‘D’ anion is substituted into the original lattice (A2B), what is the strain energy associated. What changes are expected in this cell (that is, type of defects that are forming) and also list down the new chemical formula of this system (if any change to the original is seen)?

Take note that in (ii) and (iii), we are not referring to a site, but an atom/cell. Radii (in nm) of A, B, C and E are 0.099, 0.133, 0.051, and 0.140, respectively. C is a cation with +2 charge; and E is an anion with a –1 charge.

5. A diffusion couple is prepared using BCC pure tungsten and a tungsten-1 at% thorium alloy. After several minutes of heat treatment at 2000°C, a transition zone of 0.01 cm thickness is established. What is the flux of thorium atoms (in atoms/cm2 -s) if diffusion is due to (a) volume diffusion; (b) grain boundary diffusion; and (c) surface diffusion?

Subsequently, calculate the effective diffusion coefficient and flux if the volume fraction of atoms diffusing through volume is 0.8, through grain boundary is 0.09 and through free surface is 0.11.
Use the following information:
– Assume that the diffusion process to be steady state.
– The lattice parameter of BCC tungsten is 3.165 Å.

– Volume (or bulk) diffusivity of thorium atoms, Dv = 1.0 exp(-60400/T) cm2/s, its grain boundary diffusivity is Db = 0.74 exp (-45300/T) cm2/s, and its free surface diffusivity is Df = 0.47 exp(-33400/T) cm2/s.

Answer
Recent Solved Questions
No Need To Pay Extra
  • Turnitin Report

    $10.00
  • Proofreading and Editing

    $9.00
    Per Page
  • Consultation with Expert

    $35.00
    Per Hour
  • Live Session 1-on-1

    $40.00
    Per 30 min.
  • Quality Check

    $25.00
  • Total
    Free

New Special Offer

Get 30% Off

UP TO 15 % DISCOUNT

Get Your Assignment Completed At Lower Prices

Plagiarism Free Solutions
100% Original Work
24*7 Online Assistance
Native PhD Experts
Hire a Writer Now
My Assignment Help SG Services
My Assignment Help SG

Rated 4.9/5 Based on 22945 Singaporean Students